Metathesis of fatty acid ester derivatives in 1,1-dialkyl and 1,2,3-trialkyl imidazolium type ionic liquids

Priya A. Thomas; Bassy Boas Marvey; Eno E. Ebenso

doi:10.3390/ijms12063989

Metathesis of fatty acid ester derivatives in 1,1-dialkyl and 1,2,3-trialkyl imidazolium type ionic liquids

Priya A. Thomas, Bassy Boas Marvey, Eno E. Ebenso

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1-4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF ₆ ^-, BF ₄ ^- and NTf ₂ ^-) using the gas chromatographic technique. Best catalytic performance was obtained in [bdmim][X] type ionic liquids when compared with [bmim][X] type ionic liquids. Catalyst recycling studies were also carried out in the room temperature ionic liquids (RTILs) with catalysts 1-4 in order to explore their possible industrial application.

Original language	English
Pages (from-to)	3989-3997
Number of pages	9
Journal	International Journal of Molecular Sciences
Volume	12
Issue number	6
DOIs	https://doi.org/10.3390/ijms12063989 https://doi.org/10.3390/ijms12063989
Publication status	Published - Jun 2011
Externally published	Yes

Keywords

Methyl oleate
Methyl ricinoleate
Self-metathesis
[bdmim][X]
[bmim][X]

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title = "Metathesis of fatty acid ester derivatives in 1,1-dialkyl and 1,2,3-trialkyl imidazolium type ionic liquids",

abstract = "The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1-4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF 6 -, BF 4 - and NTf 2 -) using the gas chromatographic technique. Best catalytic performance was obtained in [bdmim][X] type ionic liquids when compared with [bmim][X] type ionic liquids. Catalyst recycling studies were also carried out in the room temperature ionic liquids (RTILs) with catalysts 1-4 in order to explore their possible industrial application.",

keywords = "Methyl oleate, Methyl ricinoleate, Self-metathesis, [bdmim][X], [bmim][X]",

author = "Thomas, \{Priya A.\} and Marvey, \{Bassy Boas\} and Ebenso, \{Eno E.\}",

year = "2011",

month = jun,

doi = "10.3390/ijms12063989",

language = "English",

volume = "12",

pages = "3989--3997",

journal = "International Journal of Molecular Sciences",

issn = "1661-6596",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

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TY - JOUR

T1 - Metathesis of fatty acid ester derivatives in 1,1-dialkyl and 1,2,3-trialkyl imidazolium type ionic liquids

AU - Thomas, Priya A.

AU - Marvey, Bassy Boas

AU - Ebenso, Eno E.

PY - 2011/6

Y1 - 2011/6

N2 - The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1-4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF 6 -, BF 4 - and NTf 2 -) using the gas chromatographic technique. Best catalytic performance was obtained in [bdmim][X] type ionic liquids when compared with [bmim][X] type ionic liquids. Catalyst recycling studies were also carried out in the room temperature ionic liquids (RTILs) with catalysts 1-4 in order to explore their possible industrial application.

AB - The self-metathesis of methyl oleate and methyl ricinoleate was carried out in the presence of ruthenium alkylidene catalysts 1-4 in [bmim] and [bdmim][X] type ionic liquids (RTILs) (X = PF 6 -, BF 4 - and NTf 2 -) using the gas chromatographic technique. Best catalytic performance was obtained in [bdmim][X] type ionic liquids when compared with [bmim][X] type ionic liquids. Catalyst recycling studies were also carried out in the room temperature ionic liquids (RTILs) with catalysts 1-4 in order to explore their possible industrial application.

KW - Methyl oleate

KW - Methyl ricinoleate

KW - Self-metathesis

KW - [bdmim][X]

KW - [bmim][X]

UR - https://www.scopus.com/pages/publications/79959753960

U2 - 10.3390/ijms12063989

DO - 10.3390/ijms12063989

M3 - Article

C2 - 21747719

SN - 1661-6596

VL - 12

SP - 3989

EP - 3997

JO - International Journal of Molecular Sciences

JF - International Journal of Molecular Sciences

IS - 6

ER -

Metathesis of fatty acid ester derivatives in 1,1-dialkyl and 1,2,3-trialkyl imidazolium type ionic liquids

Abstract

Keywords

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