Synthesis and structure of a binuclear Cu(II) complex of 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol

Bassy Boas Marvey; Yilma Gultneh; Ray Butcher

doi:10.3390/i7050179

Synthesis and structure of a binuclear Cu(II) complex of 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol

Bassy Boas Marvey^*, Yilma Gultneh, Ray Butcher

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The synthesis and crystal structure of Cu(II) complex of a binucleating tridentate ligand 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol (I) is being reported. The two chelating bispicolylamine arms in I are tethered by a 2-hydroxypropyl group with Cu(II) coordinating in a slightly distorted square planar geometry to give [Cu2(I)(OH2)(Cl)](ClO 4)3•2H2O (II). The crystal data for II: Triclinic, space group P1 with cell dimensions of a = 13.345 (4) Å, b = 13.873 (4) Å, c = 12.867 (2) Å, α = 111.68 (2)° , β = 100.34 (2)° , γ = 65.83 (2)° , V = 2018.4 (9) Å3, F.W. = 962.46, ρcalc = 1.583 g cm -3 for Z = 2, μ = 13.93 cm-1. © 2006 by MDPI.

Original language	English
Pages (from-to)	179-185
Number of pages	7
Journal	International Journal of Molecular Sciences
Volume	7
Issue number	5-6
DOIs	https://doi.org/10.3390/i7050179 https://doi.org/10.3390/i7050179
Publication status	Published - 1 Jan 2006
Externally published	Yes

Keywords

1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol
Bispicolylamine
Cu(II) complex

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@article{80ddefa1d8194c56bba6f2ade855c43e,

title = "Synthesis and structure of a binuclear Cu(II) complex of 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol",

abstract = "The synthesis and crystal structure of Cu(II) complex of a binucleating tridentate ligand 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol (I) is being reported. The two chelating bispicolylamine arms in I are tethered by a 2-hydroxypropyl group with Cu(II) coordinating in a slightly distorted square planar geometry to give [Cu2(I)(OH2)(Cl)](ClO 4)3•2H2O (II). The crystal data for II: Triclinic, space group P1 with cell dimensions of a = 13.345 (4) {\AA}, b = 13.873 (4) {\AA}, c = 12.867 (2) {\AA}, α = 111.68 (2)° , β = 100.34 (2)° , γ = 65.83 (2)° , V = 2018.4 (9) {\AA}3, F.W. = 962.46, ρcalc = 1.583 g cm -3 for Z = 2, μ = 13.93 cm-1. {\textcopyright} 2006 by MDPI.",

keywords = "1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol, Bispicolylamine, Cu(II) complex",

author = "Marvey, {Bassy Boas} and Yilma Gultneh and Ray Butcher",

year = "2006",

month = jan,

day = "1",

doi = "10.3390/i7050179",

language = "English",

volume = "7",

pages = "179--185",

journal = "International Journal of Molecular Sciences",

issn = "1661-6596",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "5-6",

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TY - JOUR

T1 - Synthesis and structure of a binuclear Cu(II) complex of 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol

AU - Marvey, Bassy Boas

AU - Gultneh, Yilma

AU - Butcher, Ray

PY - 2006/1/1

Y1 - 2006/1/1

N2 - The synthesis and crystal structure of Cu(II) complex of a binucleating tridentate ligand 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol (I) is being reported. The two chelating bispicolylamine arms in I are tethered by a 2-hydroxypropyl group with Cu(II) coordinating in a slightly distorted square planar geometry to give [Cu2(I)(OH2)(Cl)](ClO 4)3•2H2O (II). The crystal data for II: Triclinic, space group P1 with cell dimensions of a = 13.345 (4) Å, b = 13.873 (4) Å, c = 12.867 (2) Å, α = 111.68 (2)° , β = 100.34 (2)° , γ = 65.83 (2)° , V = 2018.4 (9) Å3, F.W. = 962.46, ρcalc = 1.583 g cm -3 for Z = 2, μ = 13.93 cm-1. © 2006 by MDPI.

AB - The synthesis and crystal structure of Cu(II) complex of a binucleating tridentate ligand 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol (I) is being reported. The two chelating bispicolylamine arms in I are tethered by a 2-hydroxypropyl group with Cu(II) coordinating in a slightly distorted square planar geometry to give [Cu2(I)(OH2)(Cl)](ClO 4)3•2H2O (II). The crystal data for II: Triclinic, space group P1 with cell dimensions of a = 13.345 (4) Å, b = 13.873 (4) Å, c = 12.867 (2) Å, α = 111.68 (2)° , β = 100.34 (2)° , γ = 65.83 (2)° , V = 2018.4 (9) Å3, F.W. = 962.46, ρcalc = 1.583 g cm -3 for Z = 2, μ = 13.93 cm-1. © 2006 by MDPI.

KW - 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol

KW - Bispicolylamine

KW - Cu(II) complex

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U2 - 10.3390/i7050179

DO - 10.3390/i7050179

M3 - Article

SN - 1661-6596

VL - 7

SP - 179

EP - 185

JO - International Journal of Molecular Sciences

JF - International Journal of Molecular Sciences

IS - 5-6

ER -

Synthesis and structure of a binuclear Cu(II) complex of 1,3-bis [N,N-bis(2-picolyl)amino]propan-2-ol

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